Note that the vice wheel colors are upside down relative to the virtue wheel. The primary vices are Arrogance or Hatefulness, Doubt or Fear, and Despair or Hurtfulness. These are the secondary virtues taken to an extreme.
Thus the furthest point from any virtue is the vice for its complement. Although the vice for Loving and Caring is Lustful or Dependent, the vice perhaps “opposite” it is Arrogant or Hateful.